个人主页请点击访问:https://person.zju.edu.cn/0009128 高翔 副教授,博士,博导 化学工程联合国家重点实验室(浙江大学) |
简历
2009年11月-今,浙江大学化学与生物工程学院
2005年-2009年,McMaster University,加拿大,博士
2002年-2005年,天津大学,硕士
1998年-2002年,天津大学,学士
研究兴趣
电子化学品开发
锂离子电池材料研究
聚合物新材料研发
微通道及连续流反应
人工智能
精细化学品工艺开发
人工智能自优化实验系统设计
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3D打印多形状记忆智能材料
多形状记忆智能材料的设计及制备
基于新型电极粘结剂动力锂电池
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聚烯烃锂电池隔膜挤出拉伸加工
主要在研项目
本征可弹性拉伸锂离子全电池制备及其结构与性能实时分析(国家自然科学基金项目)
导电、导离子、高粘弹性理想电极粘结剂的制备与性能研究(国家自然科学基金项目)
聚合物分子链梯度结构设计实现多形状记忆功能的研究(国家自然科学基金项目)
活性自由基高内相(细)乳液聚合过程研究(国家自然科学基金项目)
解决高比容量锂离子电池寿命过短问题的关键技术研究(浙江省科学技术厅课题)
活性自由基乳液模板聚合法制备高性能聚合物多孔隔膜(教育部博士点基金)
聚合物锂离子电池凝胶电解质的研究(浙江省科学技术厅课题)
辐照交联动力锂电池隔离膜材料的研究(浙江省科学技术厅课题)
授权专利:
1. 一种基于硅的锂离子电池负极,ZL 201810122407.X,授权日期:2020年12月29日,高翔,魏迪锋,罗英武
2. 一种窄分子量分布的多嵌段共聚物及其制备方法, ZL 201910285998.7,授权日期:2020年4月28日,方进伟, 罗英武,高翔,李伯耿
3. 一种锂离子电池可拉伸电极及其制备方法,ZL201710771001.X,高翔,周傲,罗英武,授权日期: 2019年12月31日
4. 一种嵌段共聚物/碳纳米管复合导电弹性体的制备方法, ZL201710770987.9,周傲,高翔,罗英武,授权日期:2019年07月23日,
5. 一种采用嵌段共聚物胶乳制备多相聚合物材料的方法,ZL201710548047.5,高翔,李宏泽,罗英武,授权日期:2019年4月19日
6. 一种基于硅的锂离子电池负极及其制备方法,ZL201610142109.8,高翔,张帆,罗英武,授权日期:2019年02月05日
7. 一种高比能量密度锂离子电池,ZL201610600899.X,高翔、张帆、罗英武、郑哲楠,授权日期:2019年5月28日
8. 一种锂电池用可热交联聚合物电解质膜的制备方法, ZL201610270636.7,郑哲楠,黄杰,高翔,王永常,罗英武,授权日期:2018年05月08日
9. Block copolymer comprising a block with glass transition temperature higher than 100°C and method for preparing the same,美国专利 US 9,920,156 B2,许少宏,高翔,罗英武,授权日期:2018年3月20日
10. 一种硫正极用水基电极粘结剂及制备方法,ZL201610832622.X,高翔,李丽红,罗英武,朱世平,授权日期:2018年4月27日,
11. 一种水基电极粘结剂及制备方法,ZL201610671015.X,高翔,郑哲楠,罗英武,张帆,授权日期:2018年2月2日
12. 嵌段共聚物增韧剂及制备方法与应用,ZL201510297485.X,朱月,高翔,罗英武,授权日期:2018年1月12日
13. 基于嵌段共聚物的丙烯腈-苯乙烯-丙烯酸酯韧性树脂的制备方法,ZL201510393636.1,黄杰,高翔,罗英武,授权日期:2017年10月31日
14. Poly((meth)acrylic acid-b-styrene-b-butadiene-b-styrene) block copolymer latex and method for preparing the same, 美国专利,专利号 US 9,328,234 B2,罗英武,魏任重,高翔,授权日期:2016年5月3日
15. 聚((甲基)丙烯酸-b-苯乙烯-b-(异戊二烯-co-丁二烯)-b-苯乙烯)嵌段共聚物胶乳及制备方法,ZL201410269519.X,高翔,罗英武,授权日期:2016年8月24日
16. Method for preparing porous anti-reflective thin film composed of hollow polymer nanoparticles, 美国专利,专利号 US 9,180,486 B2, 孙志娟,高翔,罗英武,授权日期:2015年11月10日
17. 一种辐照交联锂离子电池隔膜及其制备方法, ZL201310196439.1,高翔、盛伟、 李伯耿、罗英武、林叶刚、王永常,授权日期:2015年4月29日
18. 含玻璃化温度高于100oC嵌段的嵌段共聚物及制备方法,ZL201210243061.1,许少宏,高翔,罗英武,授权日期:2014年7月16日
19. 高内相乳液可逆加成断裂链转移聚合制备多孔材料的方法,王安妮,高翔,罗英武,ZL201110370935.5,授权日期:2014年6月4日
20. 一种V型梯度共聚物及其制备方法, ZL201210387662.X,郭云龙,高翔,罗英武,授权日期:2014年4月16日
21. 聚苯乙烯-b-聚丁二烯嵌段共聚物纳米胶乳及其制备方法,ZL201210084866.6,魏任重,高翔,罗英武,授权日期:2014年1月29日
22. 由聚合物纳米中空胶囊制备超级绝热聚合物材料的方法,ZL201110289648.1,罗英武,高翔,叶长怀,授权日期:2013年8月7日
23. 聚((甲基)丙烯酸-b-苯乙烯-b-丁二烯-b-苯乙烯)嵌段共聚物胶乳及其制备方法,ZL201210067021.6,罗英武,魏任重,高翔,授权日期:2013年9月25日
24. 聚((甲基)丙烯酸-b-丁二烯)嵌段共聚物及其制备方法,ZL201110119838.9,魏任重,高翔,罗英武,授权日期:2012年11月14日
代表性论文
[1] Zhang, F.; Luo, Y.; Gao, X.*; Wang, R., Copolymerized Sulfur with Intrinsically Ionic Conductivity, Superior Dispersibility, and Compatibility for All-Solid-State Lithium Batteries, Acs Sustainable Chemistry & Engineering, 2020, 8, 12100-12109.
[2] Yang, Z; Luo, Y.; Gao, X.*; Wang, R.*, High-Safety All-Solid-State Lithium-Ion Battery Working at Ambient Temperature with In Situ UV-Curing Polymer Electrolyte on the Electrode, Chemelectrochem, 2020, 7, 2599-2607.
[3] Yang, C.; Gao, X.; Luo, Y.*, End-block-curing ABA triblock copolymer towards dielectric elastomers with both high electro-mechanical performance and excellent mechanical properties, Chemical Engineering Journal, 2020, 382, 123037.
[4] Fang, J.; Gao, X.*; Luo, Y.*, Synthesis of (hard-soft-hard)(x) multiblock copolymers via RAFT emulsion polymerization and mechanical enhancement via block architectures. Polymer, 2020, 201, 122602.
[5] Jin, J.; Gao, X.; Luo, Y.*, Dielectric elastomer film with anisotropic actuation deformation on film plane. Journal of Applied Polymer Science, 2020, 137, 48795
[6] Zheng, Z.; Gao, X.*; Luo, Y., Influence of copolymer chain sequence on electrode latex binder for lithium-ion batteries. Colloid and Polymer Science 2019, 297, 1287-1299.
[7] Li, H.; Luo, Y.; Gao, X.*, Preparation of Soft Shape Memory Polymer and Its Application as a Compliant Thermal-Triggered Gripper. Macromolecular Chemistry and Physics 2019, 220, 1900229.
[8] Huang J.*, Luo, Y.; Gao, X.*, Morphology and mechanical properties of Acrylonitrile-styrene-acrylate toughened plastics with block copolymer chain structure. Polymer Engineering and Science 2019, 59, 389-395.
[9] Wei, D.; Mao, J.; Zheng, Z.; Fang, J.; Luo, Y.; Gao, X.*, Achieving a high loading Si anode via employing a triblock copolymer elastomer binder, metal nanowires and a laminated conductive structure. Journal of Materials Chemistry A 2018, 6, 20982-20991.
[10] Liu, D.; Wang, J.; Zhang, Y.; Liu, J.; Li, H.; Zhou, L.; Wu, S.*; Gao, X.*, Preparation of core-shell structured Au@SiO2 nanocomposite catalyst with Au core size below 2 nm without high-temperature calcination procedure. Journal of Materials Science, 2018, 53, 8086-8097.
[11] 高翔*; 国媛; 魏迪锋; 罗英武; 苏荣欣, 锂离子电池硅基负极黏结剂的研究新进展. 化工学报 2018, 69, 4605-4613.
[12] 高翔*; 叶向群; 朱明乔; 何潮洪, 比较教学法在化工原理实验课程教学中的应用. 实验室研究与探索 2018, 37, 215-218.
[13] Zhou, A.; Sim, R.; Luo, Y.; Gao, X.*, High-performance stretchable electrodes prepared from elastomeric current collectors and binders. Journal of Material Chemistry A 2017, 5, 21550-21559.
[14] Li, H.; Luo, Y.; Gao, X.*, Core-shell nano-latex blending method to prepare multi-shape memory polymers. Soft Matter 2017, 13, 5324-5331.
[15] Wang, S.; Li, J. X.; Qi, M. F.; Gao, X.; Wang, W. J. *, Toward Maximizing the Mechanical Property of Interconnected Macroporous Polystyrenes Made from High Internal Phase Emulsions. Langmuir 2017, 33, 14295-14303.
[16] 李丽红; 王永常; 高翔*; 朱世平, 新型锂硫电池硫正极水基粘结剂的制备研究. 高校化学工程学报 2017, 3, 669-678.
[17] Zheng, Z.; Gao, X.*; Luo, Y.; Zhu, S., Employing Gradient Copolymer To Achieve Gel Polymer Electrolytes with High Ionic Conductivity. Macromolecules 2016, 49, 2179-2188.
[18] Li, H.; Gao, X.*; Luo, Y., Multi-shape memory polymers achieved by the spatio-assembly of 3D printable thermoplastic building blocks. Soft Matter 2016, 12, 3226-3233.
[19] Zhu, Y.; Gao, X.; Luo, Y.*, Core-shell particles of poly(methyl methacrylate)-block-poly(n-butyl acrylate) synthesized via reversible addition-fragmentation chain-transfer emulsion polymerization and the polymer's application in toughening polycarbonate. Journal of Applied Polymer Science 2016, 133.
[20] Yan, K.; Gao, X.; Luo, Y.*, Kinetics of RAFT Emulsion Polymerization of Styrene Mediated by Oligo(Acrylic Acid-b-Styrene) Trithiocarbonate. AICHE Journal 2016, 62, 2126-2134.
[21] Yan, K.; Gao, X.*; Luo, Y.*, Well-Defined High Molecular Weight Polystyrene with High Rates and High Livingness Synthesized via Two-Stage RAFT Emulsion Polymerization. Macromolecular Rapid Communications 2015, 36, 1277-1282.
[22] Yan, K.; Gao, X.*; Luo, Y.*, Correlation between polydispersities of molecular weight distribution and particle size distribution in RAFT Emulsion Polymerization of Styrene. Journal of Polymer Science Part a-Polymer Chemistry 2015, 53, 1848-1853.
[23] Luo, Y.; Wang, A.-N.; Gao, X.*, One-pot interfacial polymerization to prepare PolyHIPEs with functional surface. Colloid and Polymer Science 2015, 293, 1767-1779.
[24] Guo, Y.; Gao, X.*; Luo, Y.*, Suppressing the Long-Chain Branching in the Synthesis of Poly(styrene-b-butyl acrylate-b-styrene) in RAFT Emulsion Polymerization by Tuning the Interfacial Properties. Journal of Polymer Science Part a-Polymer Chemistry 2015, 53, 1464-1473.
[25] Guo, Y.; Gao, X.*; Luo, Y.*, Mechanical Properties of Gradient Copolymers of Styrene and n-Butyl Acrylate. Journal of Polymer Science Part B-Polymer Physics 2015, 53, 860-868.
[26] Gao, X.*; Sheng, W.; Wang, Y.; Lin, Y.; Luo, Y.; Li, B.-G., Polyethylene battery separator with auto-shutdown ability, thermal stability of 220 °C, and hydrophilic surface via solid-state ultraviolet irradiation. Journal of Applied Polymer Science 2015, 132.
[27] Zhu, Y.; Bi, S.; Gao, X.; Luo, Y.*, Comparison of RAFT Ab Initio Emulsion Polymerization of Methyl Methacrylate and Styrene Mediated by Oligo(methacrylic acid-b-methyl methacrylate) Trithiocarbonate Surfactant. Macromolecular Reaction Engineering 2015, 9, 503-511.
[28] Guo, Y.; Zhang, J.; Xie, P.; Gao, X.*; Luo, Y.*, Tailor-made compositional gradient copolymer by a many-shot RAFT emulsion polymerization method. Polymer Chemistry 2014, 5, 3363-3371.
[29] Huang, J.; Zhao, S.; Gao, X.; Luo, Y.*; Li, B., Ab Initio RAFT Emulsion Copolymerization of Styrene and Acrylonitrile. Industrial & Engineering Chemistry Research 2014, 53, 7688-7695.
[30] Huang, J.; Zhao, S.; Gao, X.; Luo, Y.*; Li, B., RAFT Ab Initio Emulsion Polymerization of Styrene Using Poly(acrylic acid)-b-polystyrene Trithiocarbonate of Various Structures as Mediator and Surfactant. Macromolecular Reaction Engineering 2014, 8, 696-705.
[31] Luo, Y.; Guo, Y.; Gao, X.*; Li, B.-G.; Xie, T., A General Approach Towards Thermoplastic Multishape-Memory Polymers via Sequence Structure Design. Advanced Materials 2013, 25, 743-748.
[32] Luo, Y.; Wang, A.-N.; Gao, X.*, Pushing the mechanical strength of PolyHIPEs up to the theoretical limit through living radical polymerization. Soft Matter 2012, 8, 1824-1830.
[33] Luo, Y.; Wang, A.-N.; Gao, X.*, Miniemulsion template polymerization to prepare a sub-micrometer porous polymeric monolith with an inter-connected structure and very high mechanical strength. Soft Matter 2012, 8, 7547-7551.
[34] Ye, X.; Luo, Y.; Gao, X.*; Zhu, S.*, Design and evaluation of a thermochromic roof system for energy saving based on poly(N-isopropylacrylamide) aqueous solution. Energy and Buildings 2012, 48, 175-179.
[35] Zhou, D.; Gao, X.; Wang, W. J.; Zhu, S.*, Termination of Surface Radicals and Kinetic Modeling of ATRP Grafting from Flat Surfaces by Addition of Deactivator. Macromolecules 2012, 45, 1198-1207.
[36] Gao, X.; Zhu, S.*, Modeling Analysis of Chain Transfer in Reversible Addition-Fragmentation Chain Transfer Polymerization. Journal of Applied Polymer Science 2011, 122, 497-508.
[37] Feng, W.; Gao, X.; McClung, G.; Zhu, S.*; Ishihara, K.; Brash, J. L., Methacrylate polymer layers bearing poly(ethylene oxide) and phosphorylcholine side chains as non-fouling surfaces: In vitro interactions with plasma proteins and platelets. Acta Biomaterialia 2011, 7, 3692-3699.
[38] Gao, X.; Zhu, S.*; Sheardown, H.; Brash, J. L., Nanoscale patterning through self-assembly of hydrophilic block copolymers with one chain end constrained to surface. Polymer 2010, 51, 1771-1778.
[39] Gao, X.; Feng, W.; Zhu, S.*; Sheardown, H.; Brash, J. L., Kinetic Modeling of Surface-Initiated Atom Transfer Radical Polymerization. Macromolecular Reaction Engineering 2010, 4, 235-250.
[40] Gao, X.; Kucerka, N.; Nieh, M.-P.; Katsaras, J.; Zhu, S.*; Brash, J. L.; Sheardown, H., Chain Conformation of a New Class of PEG-Based Thermoresponsive Polymer Brushes Grafted on Silicon as Determined by Neutron Reflectometry. Langmuir 2009, 25, 10271-10278.
[41] Gao, X.; Feng, W.; Zhu, S.*; Sheardown, H.; Brash, J. L., A facile method of forming nanoscale patterns on poly(ethylene glycol)-based surfaces by self-assembly of randomly grafted block copolymer brushes. Langmuir 2008, 24, 8303-8308.